Synthesis conditions of butyl acetate were studied with catalysis by Waugh structure molybdenum-manganese polyoxometalate. Optimum reaction condition was determined as the following: alcohol-acid molar ratio 1:3, catalyst quantity 0.4 g, methylbenzene 5 ml as water-carrying agent, reaction time 120 min, selectivity 100%, esterification rate 93.50%.
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