Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry
ISSN: 0975-413X
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Abstract
Palladium catalyzed ring opening of meso bicyclic hydrazines with catechol and resorcinol
Author(s): K. Rameshbabu, K. Venu Gopal, A. Jayaraju, G. Nageswara Reddy, J. SreeramuluA novel method for the synthesis of disubstituted cyclopentenes with phenolic hydroxyl group has been investigated. This methodology involves the palladium catalyzed ring opening of azabicyclichydrazines with catechols and resorcinolthatlead to the formation of 1,4-disubstituted cyclopentenes with potent phenolic hydroxyl group. This method is useful for synthesis of benzoquinone appended cyclopentenes, which are known to be highly bioactive molecules.
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Citations : 15261
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