Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry
ISSN: 0975-413X
Abstract
Magnitude Bode Plot Analysis of Solid Polymer Electrolyte PMMA Complexed with Adipic Acid
Author(s): K. P. Radha, P. Mahalakshmi and S.ChitraIn the present work, proton conducting solid polymer electrolyte have been prepared using PMMA and adipic acid (C6H10O4) by Solution Casting Technique. From the Magnitude Bode Plot, it has been observed that the Ohmic resistance dominates the impedance at the highest frequencies and it can be read from the high frequency horizontal plateau region. Argand plots of both pure PMMA and adipic acid added electrolyte are incomplete half semicircle suggesting the Non - Debye nature of the polymer electrolytes. At higher frequencies due to the periodic reversal of the electric field there is no excess ion diffusion in the field direction. The presence of long tail in the modulus plot may be due to the large capacitance associated with the electrodes.
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