Der Pharma Chemica
Journal for Medicinal Chemistry, Pharmaceutical Chemistry, Pharmaceutical Sciences and Computational Chemistry
ISSN: 0975-413X
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Abstract
Application of Beckmann rearrangement in the synthesis of indophenazino fused pyrrolo [3,2-c] azepine and pyrrolo [3,2-c] diazepine derivatives
Author(s): Veena Yadav, Nishant Yadav, Meenakshi Agrawal and D. KishoreA variety of ketoximes of indophenazino fused carbazole 5a and azacarbazoles 5(b-e), easily prepared from the corresponding ketones 4(a-e) undergo the Beckmann rearrangement upon treatment with 2,4,6-trichloro [1,3,5] triazine in N,N-dimethylformamide at room temperature afforded indophenazino fused pyrrolo [3,2-c] azepine (6a) and indophenazino fused pyrrolo [3,2-c] diazepines derivatives 6(b-e) in moderate to goog yields.
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